Although practicing the previous chromatic scale will certainly provide        you with great benefits (like limbering up your fingers), it is admittedly        not a whole lot of fun. Most people love to play "chords" on the guitar.        Playing a chord involves using your pick to strike at least two notes (often        more) on the guitar simultaneously. The following are three of the most        common, and easy to play chords on the guitar. 
This diagram illustrates the first chord we are going to play, a G major          chord (often simply called a "G chord"). Take your second finger, and          put it on the third fret of the sixth string. Next, take your first finger,          and put it on the second fret of the fifth string. Lastly, put your third          finger on the third fret of the first string. Make sure all of your fingers          are curled, and are not touching any strings they're not supposed to.          Now, using your pick, strike all six strings in one fluid motion. Notes          should ring all together, not one at a time (this could take some practice).          Voila! Your first chord.
Now, check to see how you did. While still holding down the chord with          your fretting hand, play each string (starting with the sixth) one at          a time, listening to be sure each note rings out clearly. If not, study          your hand to determine why it doesn't. Are you pressing hard enough? Is          one of your other fingers touching that string, which is preventing it          from sounding properly? These are the most common reasons why a note does          not sound. If you're have trouble, read this feature on getting          your chords to ring clearly.  guitar.about.com
